For every ace Kyrgios serves during events in Australia in January, he will donate AUS$200 to help relief efforts fighting fires in the country.
At least 18 people have died as bush fires continue.
The air quality of the Australian tennis player's home town, Canberra, has been badly affected by ongoing blazes.
Residents there have been advised to stay indoors.
Australia's cricketers are also planning tributes and fund-raising.
Black armbands will be worn by both the Baggy Greens and Black Caps during their third Test in Sydney on Friday.
There will also be a minute's applause to honour the country's firefighters.
Officials will be monitoring smoke levels during the match in case players need to be called off the grounds to stop play.


Arsenal beat Man City 3-0 to win Community Shield
Cristiano Ronaldo hints at retirement amid 'last year' claims
Sri Lanka fight back through spinners but India 460-9
Man arrested on suspicion of fraud after security operation disrupts European Championships
Bangladesh claim first test win in Australia as Green ton in vain
