The northern section of the grain silos damaged two years ago by a blast at the Beirut port collapsed early on Tuesday after warnings the structure was leaning too far to stay up.
The crash sent a cloud of brown-grey dust billowing over the waterfront, the LBCI television station reported. There were no immediate reports of injuries.
The huge explosion at the port on August 4, 2020, killed more than 220 people and gutted the northern section of the grain silos, leaving wheat and corn spilling out in the sun.
Recently, a fire had been smouldering in the silos for weeks, which officials said was the result of summer heat igniting fermenting grain left rotting.
Part of the structure collapsed on July 31 and another section fell on August 4, the second anniversary of the blast.
On Sunday, the health ministry said dust samples from around the port showed that the air contained high amounts of common mould, which would not be dangerous unless inhaled in large quantities over a long period of time.
Eight Israeli airstrikes have hit the Abu al-Duhur military airbase in northwestern Syria early on Tuesday, targeting the runway and storage facilities, Syria's state-run Ekhbariya said, citing a military source.
Two students were killed in a shooting at a high school in the southern Philippines on Tuesday, one of them the gunman, officials said, in the second such incident in the country in less than two months.
The Supreme Court of Pakistan has ordered on Tuesday that former Prime Minister Imran Khan be moved to hospital from jail, his Pakistan Tehreek-e-Insaf party said, meeting a longstanding demand of his party and family, who had raised concerns about his health.
A Russian missile attack has killed 10 people and injured a further eight in a village in Ukraine's northeastern Kharkiv region, the regional governor said on Tuesday.
President Donald Trump said on Monday Iran would not make the deal he thinks is needed to end a war with the US and should surrender as talks between the countries remained stalled.